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I've been developing films and printing for over 50 years now. I've seen a few developers in my darkrooms, from Definol to PMK, from ID11 to Acutol. So it takes a lot to wow me. They've all got their strengths and weaknesses, their plusses and minuses, and most do a very good job after you have learned their ways. But, when I tried 510-Pyro I knew I'd found something very special. In The Art of Black and White Developing I talk about this developer at length, showing the tests and results of 510-Pyro pitted against some other greats like PMK and Pyrocat. I don't want to spoil your read of the book so I'll not give away too much here but, shall we say, wow!
A new generation developer
510-Pyro is one of the new generation of staining and tanning developers, and said to be similar to Pyrocat or PMK. It was formulated by Jay DeFehr in the USA and arrived on the scene with amazing claims of very fine grain, high acutance, good stain, and extreme longevity (as a single stock). We've heard these before right? However, as the developer became more widely used, and people started testing it for themselves, a following took shape with photographers reporting good results with both normal development, stand and semi-stand techniques.
I found it remarkable that the developer is used at dilutions from 1+100 or 1+200 for normal development, and up to 1+500 for stand development (move over Rodinal!). This meant that the developer is extremely low cost in use, yet giving results that surpass developers costing much more. More on that later…
TMax-400 with 510-Pyro - Stand development 20 minutes at 24c. Very sharp combination with great contrast. It's good to see a pyrogallol based developer that works so well with modern T-Grain emulsions. Old formula.
The developer uses Pyrogallol, the second oldest developing agent ever used (after gallic acid). It became very popular in the late 19th century until displaced by the ubiquitous Metol. However, pyrogallol has two main advantages over metol. These are:
1. An oxidisation stain created by Pyro, which becomes a natural filter to tame highlights and ease printing
2. Tanning or hardening of the gelatine emulsion which both protects the negative from damage and reduces developer movement through the emulsion creating higher beneficial acutance in the image. This acutance is produced even when rotary processed in a job (for instance), something difficult to do with constant agitation.
These two benefits are enormous when done right; and the hunt for a way to use Pyro has continued for over a century. 510-Pyro claims to have achieved not only these two benefits (as PMK did in 1991 right?) but also the Holy Grail of photography, ultra fine grain with high sharpness. I want to add yet another additional benefit for me, a single solution stock (no mixing of A, B) that keeps for years.
That's a long list of impressive claims so maybe it's time we looked at DeFehr's 510-Pyro more closely and gave it a run for it's money against the big boys of modern staining developers PMK and Pyrocat.
Formula for 510-Pyro stock:
TEA (Triethanolamine) 75ml
Ascorbic Acid 5g
(updated from the original 0.25g of phenidone by Jay DeFehr "To optimize the three way relationship between pyrogallol, ascorbic acid and phenidone")
TEA to make 100ml
Use 1+100 through 1+500 with water.
TMax-400 with 510-Pyro - Stand development 20 minutes at 24c. Very sharp combination with plenty of shadow detail and tamed highlights. This method of stand development means you can process multiple films of different ISOs in the same development tank for the same time. Old formula.
The developer is designed to be extremely long lasting as stock. TEA, an organic solvent, is now well know as a preservative after the great work by Pat Gainer in this field. Unlike water, TEA does not dissolve oxygen and therefore protects the developing agents for years. Previously the king of longevity was Rodinal keeping for so long it turned brown like old tea but still worked well. PMK also keeps very well as does Pyrocat in glycol. As film photographers we never know how many times we'll develop films and so keeping quality is very important: just ask anyone who's developed their precious film only to find the developer has gone bad. So 510-Pyro's use of TEA as a solvent and protector from oxidation is ideal, 510-Pyro will last for years.
The developing agents used in 510-Pyro are Ascorbic acid, Pyrogallol and Phenidone. An unusual combination. I don't know of any other developer that has three developing agents. Of course, utilising TEA as a solvent removes the need for an anti-oxidant/preservative, so theirs no sulphite required. The TEA also provides the alkalinity to activate the developing agents so no accelerator is required. DeFehr later balanced the formula by increasing the phenidone from 0.25g in the original recipe to 0.375g in the new.
TMax-400 Stand development - old formula
All this makes a developer that is very simple to use - just one solution; use a syringe to measure, mix with water and it's ready. Add to this the extreme longevity and the very high dilution and you could have a winner on your hands.
But winning developers need more than just simplicity of use and a long lifespan, they need to produce the goods on the negative and be either on a par with the competition or better. What I found was amazing. In my book I test the developer against some of the best to see what it's really made of. Check it out The Art of Black and White Developing.
This is a popular way of using 510-Pyro, especially when you are either not sure of a developing time for your film or you are wanting a fair degree of compensation of the highlights. The best way I've found of using 510 as a stand developer is to dilute the developer in a ratio of 1 to 300 and use it at 24 degrees C. After adding the developer to the tank (no pre-soak) agitate gently for one minute, then let it stand in a 24 deg. C bath until the nine minute point. Agitate again for one minute and let stand for the rest of the time. That's it! Pour out the developer at 20 minutes and stop with a couple of thirty second water baths, fix with an alkaline fixer.
- Stand develop at 24 degrees C
- No presoak needed
- Agitate for first minute
- Agitate again at the nine minute point
- Water stop bath at 20 minutes
- Alkaline fix
If you want to know more about this developer and others buy my book. The kindle version is on special offer now on Amazon.
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Here we see 510-Pyro used with Acros at 80ISO.
The sharpness and fine grain in the negative is amazing. The tones are long with softness to the highlights and shadows full of detail.
510-Pyro brings out all the nuances in the photograph.